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Lochbaum, who formerly taught reactor operation for the Nuclear Regulatory Commission, said the pools measured about 40 feet long, 40 feet wide and 45 feet deep. The spent fuel, he added, rested at the pool's bottom and rose no higher than 15 feet from the bottom. That means that in normal operations, the spent fuel is covered by about 30 feet of cooling water.
That's 24000 cubic feet of water times 27 litres per cubic foot gives 648,000 litres of water, or 648 tonnes of water.
tuasfait:
Whether or not my outburst last night worked, now Army choppers dropped over 21 tons of water on No. 3. The riot squad is preparing to spray water now, at 11 am Tokyo time.
In addition, according to Gaianne:
At high temperature the oxide of zirconium flakes away and the zirconium keeps burning. Also, the affinity of zirconium for oxygen is so fierce at high temperatures that zirconium will pull the oxygen out of steam (vaporized water) leaving hydrogen which will burn as soon as it meets more oxygen--which is presumably what fueled the several large explosions of reactor buildings.
the tonne/ton conversion factor
We now have TWO confirmed LOCA's and subsequent H2 explosions at the Fukushima complex. To make a big H2 boom, you have to make a lot of H2, which evidently comes from this reaction: Zr + 2 H2O --> ZrO2 + 2 H2 So this means that lots of Zr fuel cladding has turned into zirconia and lots of H2, and that the really hot UO2 fuel pellets (self heating due to daughter products radioactive (via beta emission) decay) are now exposed to hot steam and some nasty "daughters" are puking out of the system via the steam vents. Just to add spice to the gumbo, Unit 3 has about 5% Mixed Oxide Fuel (plutonium 239 based, but also some Pu240). Supposedly the daughters can provide 5 to 7% of the thermal energy of a fissioning facility, but since the Unit 1 was evidently about to get changed out, this could be more like 15%. For a 480 MW unit, this would mean that 36 to 72 MW of heat had to be removed, assuming that all fission reactions were stopped by the control rod insertion. Well, that's a lot of heat. Translated, 7.5% residual heat generation is 36 MW is 122.8 MBtu/hr (millions of Btu/hr), and that is close to 126,000 lbs/hr of steam generation at atmospheric or 15,136 gallons/hr = 252 gpm water evaporation). For the metrically inclined, the 7.5% decay heat removal corresponds to an evaporation rate of 57 tonnes/hr of water. At 15%, you can double that. That's a lot of water buckets...... On the other hand, a gasoline powered water pump with a 2" pipe outlet (50 mm) might be able to do the trick, if they have them handy, and if they have a way to pump this water into the system. Power wise, they need about 25 kw engines to pump this water, or about 35 hp ones. And that is needed for EACH active reactor. Oh, BTW, they also need lots of cooling for those swimming pools where all those spent fuel rods are "cooling" off. While no where nearly as hot, take those out of water and they will also start glowing cherry red after a few minutes to a few hours. And when those catch on fire, well, that's just another massive load of stuff to hit the fan.
Zr + 2 H2O --> ZrO2 + 2 H2
So this means that lots of Zr fuel cladding has turned into zirconia and lots of H2, and that the really hot UO2 fuel pellets (self heating due to daughter products radioactive (via beta emission) decay) are now exposed to hot steam and some nasty "daughters" are puking out of the system via the steam vents. Just to add spice to the gumbo, Unit 3 has about 5% Mixed Oxide Fuel (plutonium 239 based, but also some Pu240).
Supposedly the daughters can provide 5 to 7% of the thermal energy of a fissioning facility, but since the Unit 1 was evidently about to get changed out, this could be more like 15%. For a 480 MW unit, this would mean that 36 to 72 MW of heat had to be removed, assuming that all fission reactions were stopped by the control rod insertion.
Well, that's a lot of heat. Translated, 7.5% residual heat generation is 36 MW is 122.8 MBtu/hr (millions of Btu/hr), and that is close to 126,000 lbs/hr of steam generation at atmospheric or 15,136 gallons/hr = 252 gpm water evaporation). For the metrically inclined, the 7.5% decay heat removal corresponds to an evaporation rate of 57 tonnes/hr of water. At 15%, you can double that. That's a lot of water buckets...... On the other hand, a gasoline powered water pump with a 2" pipe outlet (50 mm) might be able to do the trick, if they have them handy, and if they have a way to pump this water into the system. Power wise, they need about 25 kw engines to pump this water, or about 35 hp ones.
And that is needed for EACH active reactor.
Oh, BTW, they also need lots of cooling for those swimming pools where all those spent fuel rods are "cooling" off. While no where nearly as hot, take those out of water and they will also start glowing cherry red after a few minutes to a few hours. And when those catch on fire, well, that's just another massive load of stuff to hit the fan.
So far only Robert Alvarez claims that the spent fuel rods caught fire, while Japanese sources imply an oil fire only. There is a wide range difference between boiling (greater than 100°C) and melting (2,200°C). *Lunatic*, n. One whose delusions are out of fashion.
Anderson Cooper 360: Blog Archive - Official: Spent fuel rods exposed, heightening concerns « - CNN.com Blogs
"What we believe at this time is that there has been a hydrogen explosion in this unit due to an uncovering of the fuel in the fuel pool," Gregory Jaczko told a House energy and commerce subcommittee hearing. "We believe that secondary containment has been destroyed and there is no water in the spent fuel pool, and we believe that radiation levels are extremely high, which could possibly impact the ability to take corrective measures." The water served to both cool the uranium fuel and shield it. But once the uranium fuel was no longer covered by water, its zirconium cladding that encases the fuel rods heated, generating hydrogen, said Robert Alvarez, senior scholar at the Institute for Policy Studies and a former official with the Department of Energy. That caught fire, resulting in a situation that is "very, very serious," he told CNN. He said the next solution may involve nuclear plant workers having to take heroic acts. Asked to be more specific, he said, "This is a situation where people may be called in to sacrifice their lives. ... It's very difficult for me to contemplate that but it's, it may have reached that point."
"What we believe at this time is that there has been a hydrogen explosion in this unit due to an uncovering of the fuel in the fuel pool," Gregory Jaczko told a House energy and commerce subcommittee hearing. "We believe that secondary containment has been destroyed and there is no water in the spent fuel pool, and we believe that radiation levels are extremely high, which could possibly impact the ability to take corrective measures."
The water served to both cool the uranium fuel and shield it. But once the uranium fuel was no longer covered by water, its zirconium cladding that encases the fuel rods heated, generating hydrogen, said Robert Alvarez, senior scholar at the Institute for Policy Studies and a former official with the Department of Energy.
That caught fire, resulting in a situation that is "very, very serious," he told CNN. He said the next solution may involve nuclear plant workers having to take heroic acts. Asked to be more specific, he said, "This is a situation where people may be called in to sacrifice their lives. ... It's very difficult for me to contemplate that but it's, it may have reached that point."
The Oil Drum | Fukushima Dai-ichi status and potential outcomes
Like aluminum, zirconium and is alloys (Zircaloy-2) oxidize instantly in air. A thin film of ZrO2 is so impervious to oxygen diffusion that the reaction stops. Even in 300 C (572F) water or steam at over 1000 psi, the oxidation rate is extremely slow and corrosion properties of Zircaloy fuel cladding are outstanding and safe, AS LONG as they are not overheated and cooling water flow is maintained. In fact it is standard practice to autoclave fuel rods in hot-pressured water or steam to precoat these rods with the optimum coating of ZrO2. But these fuel rods must NEVER be overheated. That is why multiple redundant cooling systems are required. All these backup-cooling systems failed in Japan. Even after reactor shutdown, if the fuel rods are uncovered cladding temperatures can rapidly rise to 800C , or higher, due to fission product decay heat. As in any chemical reaction the rate accelerates rapidly with temperature, but in the case of zirconium, the protective character of a thin ZrO2 film is destroyed by this high temperature and catastrophic oxidation occurs. However this catastrophic oxidation occurs below the melting point, so I object to the media using the common term "meltdown" which is misleading. This loss of the last battery powered cooling, led to the fuel rods becoming uncovered in a manner similar that also occurred in the Three Mile Island accident (although due to different reasons). When overheated in steam the oxidation reaction above accelerates exponentially. As the zirconium oxidizes the coating thickens, cracks and turns white from internal fractures that increase the diffusion rate of steam to the metal. . It then has the look and mechanical properties of eggshells. Hydrogen from this process is released, but also is absorbed by the underlying metal cladding which causes embrittlement and metal fracture. Soon cracks form in the cladding releasing the trapped fission products inside. This is not "melting', but rather catastrophic disintegration of the cladding structural integrity and containment of fission products. If the process continues the cladding can fracture away exposing the fuel pellets which in the worst-case scenario can drop out and collect on the bottom of the reactor vessel. It is the worse case scenario that I believe is causing the Japanese to inject boric acid. Boron is a neutron absorber and will prevent any possibility of a pile of fuel pellets on the bottom of the vessel from going critical and restarting the chain reaction.
Like aluminum, zirconium and is alloys (Zircaloy-2) oxidize instantly in air. A thin film of ZrO2 is so impervious to oxygen diffusion that the reaction stops. Even in 300 C (572F) water or steam at over 1000 psi, the oxidation rate is extremely slow and corrosion properties of Zircaloy fuel cladding are outstanding and safe, AS LONG as they are not overheated and cooling water flow is maintained. In fact it is standard practice to autoclave fuel rods in hot-pressured water or steam to precoat these rods with the optimum coating of ZrO2.
But these fuel rods must NEVER be overheated. That is why multiple redundant cooling systems are required. All these backup-cooling systems failed in Japan. Even after reactor shutdown, if the fuel rods are uncovered cladding temperatures can rapidly rise to 800C , or higher, due to fission product decay heat. As in any chemical reaction the rate accelerates rapidly with temperature, but in the case of zirconium, the protective character of a thin ZrO2 film is destroyed by this high temperature and catastrophic oxidation occurs. However this catastrophic oxidation occurs below the melting point, so I object to the media using the common term "meltdown" which is misleading.
This loss of the last battery powered cooling, led to the fuel rods becoming uncovered in a manner similar that also occurred in the Three Mile Island accident (although due to different reasons). When overheated in steam the oxidation reaction above accelerates exponentially. As the zirconium oxidizes the coating thickens, cracks and turns white from internal fractures that increase the diffusion rate of steam to the metal. . It then has the look and mechanical properties of eggshells. Hydrogen from this process is released, but also is absorbed by the underlying metal cladding which causes embrittlement and metal fracture. Soon cracks form in the cladding releasing the trapped fission products inside. This is not "melting', but rather catastrophic disintegration of the cladding structural integrity and containment of fission products. If the process continues the cladding can fracture away exposing the fuel pellets which in the worst-case scenario can drop out and collect on the bottom of the reactor vessel. It is the worse case scenario that I believe is causing the Japanese to inject boric acid. Boron is a neutron absorber and will prevent any possibility of a pile of fuel pellets on the bottom of the vessel from going critical and restarting the chain reaction.
What's Behind the Two Fukushima Explosions? Does Zirconium Explode at 2,000 Degrees? | techyum ::
So...what's really behind the two Fukushima explosions? Were they hydrogen, or something else? You tell me, Dr. Fabulous. But here's what I know, and here's how an anti-nuclear activist just pissed me off by setting off my bullshit detector. CommonDreams.org has a piece by Karl Grossman, journalism professor, anti-nuke activist and author of the 1980 book Cover Up: What You Are Not Supposed to Know About Nuclear Power, that is getting a lot of play in the wake of a second hydrogen explosion at the Fukushima I plant. It appears to have been written before the second explosion. In this article, Grossman makes some claims about the element zirconium, used in the fuel cladding around the nuclear fuel, that set off my bullshit detector for no good reason. I don't, or didn't, know squat about zirconium or zircaloy. But his arguments sounded strange.
CommonDreams.org has a piece by Karl Grossman, journalism professor, anti-nuke activist and author of the 1980 book Cover Up: What You Are Not Supposed to Know About Nuclear Power, that is getting a lot of play in the wake of a second hydrogen explosion at the Fukushima I plant. It appears to have been written before the second explosion.
In this article, Grossman makes some claims about the element zirconium, used in the fuel cladding around the nuclear fuel, that set off my bullshit detector for no good reason. I don't, or didn't, know squat about zirconium or zircaloy. But his arguments sounded strange.
Behind the Hydrogen Explosion at the Fukushima Nuclear Plant | Common Dreams
Eruption of hydrogen gas as a first reaction in a loss-of-coolant accident has been discussed with great worry in U.S. government and nuclear industry literature for decades. That is because a highly volatile substance called zirconium was chosen back in the 1940's and 50's, when plans were first developed to build nuclear power plants, as the material to be used to make the rods into which radioactive fuel would be loaded. There are 30,000 to 40,000 rods--composed of twenty tons of zirconium--in an average nuclear power plant. Many other substances were tried, particularly stainless steel, but only zirconium worked well. That's because zirconium, it was found, allows neutrons from the fuel pellets in the rods to pass freely between the rods and thus a nuclear chain reaction to be sustained.
That is because a highly volatile substance called zirconium was chosen back in the 1940's and 50's, when plans were first developed to build nuclear power plants, as the material to be used to make the rods into which radioactive fuel would be loaded.
There are 30,000 to 40,000 rods--composed of twenty tons of zirconium--in an average nuclear power plant. Many other substances were tried, particularly stainless steel, but only zirconium worked well. That's because zirconium, it was found, allows neutrons from the fuel pellets in the rods to pass freely between the rods and thus a nuclear chain reaction to be sustained.
There are 30,000 to 40,000 rods--composed of twenty tons of zirconium--in an average nuclear power plant. (??)
However, those calculations are for the BWR designs by GE. Have any reactors been built that use substantially more rods per reactor, say 200 rods at any given time? If so, that should produce higher neutron flux densities and I don't know how that might impact the metallurgy, etc. "It is not necessary to have hope in order to persevere."
In boiling water reactors (BWR), the fuel is similar to PWR fuel except that the bundles are "canned"; that is, there is a thin tube surrounding each bundle. This is primarily done to prevent local density variations from affecting neutronics and thermal hydraulics of the reactor core. In modern BWR fuel bundles, there are either 91, 92, or 96 fuel rods per assembly depending on the manufacturer. A range between 368 assemblies for the smallest and 800 assemblies for the largest U.S. BWR forms the reactor core. Each BWR fuel rod is back filled with helium to a pressure of about three atmospheres (300 kPa).
For PWRs, the figures are similar so the 368 assemblies is not a typo of the kind that 4 assemblies of 92 adds up to 368 bundles.
There are about 179-264 fuel rods per fuel bundle and about 121 to 193 fuel bundles are loaded into a reactor core. Generally, the fuel bundles consist of fuel rods bundled 14x14 to 17x17.
Figures provided by Tokyo Electric Power on Thursday show that most of the dangerous uranium at the power plant is actually in the spent fuel rods, not the reactor cores themselves. The electric utility said that a total of 11,195 spent fuel rod assemblies were stored at the site. That is in addition to 400 to 600 fuel rod assemblies that had been in active service in each of the three troubled reactors. In other words, the vast majority of the fuel assemblies at the troubled reactors are in the storage pools, not the reactors.
That is in addition to 400 to 600 fuel rod assemblies that had been in active service in each of the three troubled reactors. In other words, the vast majority of the fuel assemblies at the troubled reactors are in the storage pools, not the reactors.
Danger of Spent Fuel Outweighs Reactor Threat - NYTimes.com
At Daiichi, each assembly has either 64 large fuel rods or 81 slightly smaller fuel rods, depending on the vendor who supplied it.
A modern BWR fuel assembly comprises 74 to 100 fuel rods, and there are up to approximately 800 assemblies in a reactor core, holding up to approximately 140 tons[vague] of uranium. The number of fuel assemblies in a specific reactor is based on considerations of desired reactor power output, reactor core size and reactor power density.
This is a diagram of a single fuel assembly consisting of 96 rods in 4 bundles of 24 with the corner rod of a 5x5 array missing. The cut in the middle is not really there, it's to show certain internal structures of the arrangement.
The fuel rods are 4m+ long and very thin.
There are hundreds or these hundred-rod assemblies in each reactor core. As you can see the assembly has a hole at the top through which a crane's hook could grab the assembly in order to lift it out of place or lower it down into place. So, in what may be my last act of "advising", I'll advise you to cut the jargon. -- My old PhD advisor, to me, 26/2/11
Nuclear Wasteland - IEEE Spectrum
BLUE GLOW OF SUCCESS: Fuel assemblies cool in a water pond at the French nuclear complex at La Hague. The blue light is generated by Cherenkov radiation, which arises from a particle's traveling through a medium faster than the speed of light in that medium
Japanese military helicopters and fire trucks poured water on an overheating nuclear facility on Thursday and the plant operator said electricity to part of the crippled complex could be restored in a desperate bid to avert catastrophe. Washington and other foreign capitals expressed growing alarm about radiation leaking from the earthquake-shattered plant, 240 km (150 miles) north of Tokyo. The United States said it was sending aircraft to help Americans leave Japan. ... Workers were trying to connect a 1-km (0.6-mile) long power cable from the main grid to restart water pumps to cool reactor No. 2, which does not house spent fuel rods considered the biggest risk of spewing radioactivity into the atmosphere.
Washington and other foreign capitals expressed growing alarm about radiation leaking from the earthquake-shattered plant, 240 km (150 miles) north of Tokyo. The United States said it was sending aircraft to help Americans leave Japan.
...
Workers were trying to connect a 1-km (0.6-mile) long power cable from the main grid to restart water pumps to cool reactor No. 2, which does not house spent fuel rods considered the biggest risk of spewing radioactivity into the atmosphere.
I have been watching the NHK feed and grimly laughing at the helicopter operation. Here is some info: Capacity of spent fuel pools: 1200-1500 tons water 15 meters deep Needed to cover rods: 15 meters, 400-500 tons water For reactor 3, they think there might be enough water that they only need < 100 tons, perhaps less One helicopter can drop 7.5 tons/load. BUt it can't hover, due to the radiation level. If I heard right, those on board are limited to 100 mSieverts/hour (check the time units). They had measured 250/hr at 30 meters and 87/hr at 90 meters. They dumped from 90 meters. See image. Looks more like crop dusting. There was one drop which looked a little better, but at the speed they are going, hitting the building with much is not likely.
I have been watching the NHK feed and grimly laughing at the helicopter operation. Here is some info:
Capacity of spent fuel pools: 1200-1500 tons water 15 meters deep Needed to cover rods: 15 meters, 400-500 tons water
For reactor 3, they think there might be enough water that they only need < 100 tons, perhaps less
One helicopter can drop 7.5 tons/load. BUt it can't hover, due to the radiation level. If I heard right, those on board are limited to 100 mSieverts/hour (check the time units). They had measured 250/hr at 30 meters and 87/hr at 90 meters. They dumped from 90 meters. See image. Looks more like crop dusting. There was one drop which looked a little better, but at the speed they are going, hitting the building with much is not likely.
By email from Joules Burn to Euan Means.
Needed to cover rods: 15 meters, 400-500 tons water
Fighting forest fires with planes and choppers is not an exact science, at the best of times. But at least they can get in lower than 90m.
So dropping water from helicopters is just useless. So, in what may be my last act of "advising", I'll advise you to cut the jargon. -- My old PhD advisor, to me, 26/2/11
I'm not sure for whose benefit.
And don't they have fireboats?
The range and flow of a fireboat must be an order of magnitude or two higher than a truck, surely?
(h/t DoDo) So, in what may be my last act of "advising", I'll advise you to cut the jargon. -- My old PhD advisor, to me, 26/2/11
I numbered the reactors.
No way firefighting ships can get near enough.
There's also the advantage of at least some cover from the turbine buildings.
An unprecedented attempt to douse an apparently overheating spent fuel pool with tons of coolant water at a stricken nuclear plant in Fukushima bore some fruit Thursday, but the emission of smoke newly confirmed at another pool suggests the difficulties that lie in the way of resolving the crisis triggered by the March 11 quake and tsunami. Up to 64 tons of water were aimed by helicopters and fire trucks of the Self-Defense Forces as well as a water cannon truck of the Metropolitan Police Department into the pool at the No. 3 unit of Tokyo Electric Power Co.'s Fukushima Daiichi plant. The utility said vapor rising from the partially destroyed No. 3 reactor building suggests the operation went some way toward cooling down the pool that could otherwise emit highly contaminated radioactive materials.
Up to 64 tons of water were aimed by helicopters and fire trucks of the Self-Defense Forces as well as a water cannon truck of the Metropolitan Police Department into the pool at the No. 3 unit of Tokyo Electric Power Co.'s Fukushima Daiichi plant.
The utility said vapor rising from the partially destroyed No. 3 reactor building suggests the operation went some way toward cooling down the pool that could otherwise emit highly contaminated radioactive materials.
We have had much debate about whether or not it is possible for the fission chain reaction to re-start in a pile of reactor rubble. The consensus is that this is unlikely though possible.
My intuition, and it's only that, is the players in this are thinking they are in Landscape A when the thing has undergone a Thom Catastrophe.
but I know diddly about the science and engineering involved. She believed in nothing; only her skepticism kept her from being an atheist. -- Jean-Paul Sartre
the players in this are thinking they are in Landscape A when the thing has undergone a Thom Catastrophe
Example: pumping sea water through pumps and lines not designed for sea water. Did they screen the sea water? If not, what else have they introduced to the system? Clams? Miscellaneous fish parts?
(And etc. & etc.) She believed in nothing; only her skepticism kept her from being an atheist. -- Jean-Paul Sartre
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